Abstract
AbstractA new orthogonal agent containing phototriggered o‐nitrobenzyl (NB) ether and kinetically stabilized nitrile N‐oxide moieties are synthesized and applied to the reliable catalyst‐free functionalization of materials. This orthogonal reagent enables the modification of rubbers and glass surfaces containing unsaturated bonds through the catalyst‐free [2+3] cycloaddition reaction of nitrile N‐oxide to obtain photolabile NB ether‐functionalized materials. The resulting substrates having an NB ether are suitable to undergo photocontrollable reactions with electrophiles for generating various types of functional materials.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
