Abstract
The phototransformation of the 3‐cyclohexenyloxychromenones by irradiation with a pyrex‐filtered light from a 125 W Hg vapor lamp under an inert atmosphere into the spirocyclic fused xanthenones was described. The efficacy of the protocol depended upon the position (o‐, m‐, or p‐) of the cyclohexenyloxy group appended to the 2‐aryl moiety on the chromenone nucleus, which was further invoked by steric, electronic, and proximity considerations. The structure(s) of the substrates and photoproducts were established using the spectroscopic (IR and NMR) data.
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