Abstract
Abstract 20π Antiaromatic isophlorins of N21,N22-bridged N23-alkyl-porphyrins were prepared through photoreduction with N-benzyl-1,4dihydronicotinamide or intramolecular nucleophilic alkylation at the N(24)-position. The ring structure of these N21,N22-bridged isophlorins is not highly deviated from planarity and their antiaromaticity was indicated by the great paramagnetic ring current effect.
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