Abstract
Abstract A model of NADH, 1-benzyl-1,4-dihydronicotinamide (BzlNH), reduces benzyl bromide and methyl iodide in the presence of pyridine in MeCN under irradiation of the visible light (λ > 360 nm), yielding toluene and methane as main products, respectively. Evidence is presented for occurrence of one-electron transfer from the excited state of BzlNH to benzyl bromide or methyl iodide in the primary process of the photoreduction.
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