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Abstract
A Norrish type-II reaction is proposed for the photorearrangement of allyl diphenyl phosphate to ortho-allylphenyl phenyl phosphate. In contrast to the type-II mechanism in carbonyl compounds, the reaction is postulated to proceed through a five-membered transition state to produce a phosphoranyl 1,3-biradical which subsequently rearranges to the observed product.
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