Abstract

Abstract The photoreaction of the enone (I) with cyclopentene gave the radical coupling products, (VII) and (VIII), along with the hydrogen abstraction product (VI), but not [2π+2π] photocycloadduct. On the other hand, the photoreaction of I with cyclohexene proceeded in somewhat different manner to give the [2π+2π] photocycloadduct (V) other than the hydrogen abstraction product (VI) and the radical coupling product (IX).

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