Abstract
Polynuclear complexes add a new dimension to the photochemistry of coordination compounds. Their photophysics is characterized by intercomponent transfer processes: optical electron transfer, photoinduced electron transfer, electronic energy transfer. Examples of such type of processes are discussed in some detail for polynuclear complexes containing Ru(II)-Ru(III), Ru(II)-Ru(II), Ru(II)Rh( III), and Ru(II)-Cr(III) centers.
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