Abstract
Ethyl Orange (EO) and 4-aminoazobenzene-4-sulfonic (AS) anions with Donor-∏-Acceptor structure have been intercalated into the layered double hydroxide (LDH), [Mg0.66 Al0.34 (OH)2] (CO3)0.17·0.67H2O or adsorbed on the external surface of the host by the method of ion-exchange procedures. The photoabsorption and fluorescence properties of the obtained compounds were different from the pure solid phase of EO and AS. It was suggested that the photophysical properties of guests were closely related to the geometry and electrical structure of the guest molecule, which can affect the distribution and orientation of the guests in the layers or on the surface of the host. The host–guest interactions modulate photophysical properties of guest. In addition, the guest having higher molecular dipole moments surface exchanged on MgAlCO3LDH are beneficial to the enhancement of the blue emission than that of intercalation into LDH.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.