Abstract
The photophysical properties of the first crown ether-bearing [60]fulleropyrrolidine (CFP) have been studied. The absorption and fluorescence spectra are hypsochromically shifted by metal ions complexation via intramolecular electron transfer which is confirmed by AMI computation. The third-order optical nonlinearity of CFP is measured by time-resolved degenerate four-wave-mixing experiment. The third-order optical susceptibility χ(3) of CFP is 8.97×10−14 esu. The nonlinear optical temporal response is second-order exponential, the fast process is determined as 120 ps.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
