Abstract
Substitution of chloride by azide in cyclometalated 5-R-1,3-di(2-pyridyl)-benzene platinum(II) complexes (R = mesityl, methyl or 2-thienyl) leads to novel azido complexes with an intense phosphorescence that is modulated by the nature of R. An increase of the concentration brings about to the formation of aggregates with a red-shifted emission. Furthermore, the presence of the ancillary azido group allows, via i-click reaction, the obtainment of even more emissive 1,2,3-triazole derivatives. The 1,2,3-triazolate of the mesityl and 2-thienyl N^C^N–Pt(II) complexes were characterized by X-ray diffraction analysis and their photophysical properties were deeply investigated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
