Abstract

Heterostructured polymer Langmuir–Blodgett (LB) film prepared by using poly( N-dodecylacrylamide -co- t-butyl 4-vinylphenyl carbonate) ( p(DDA- tBVPC53)) and poly( N-neopentyl methacrylamide- co-9-anthrylmethyl methacrylate) ( p(nPMA-AMMA10)) polymer LB films which can act as photogenerator layers were investigated. Patterns with a resolution of 0.75 μm were obtained on heterostructured polymer LB films composed of 4 layers of p(nPMA-AMMA10) LB film (top layers) and 40 layers of p(DDA- tBVPC53) LB film (under layers) on a silicon wafer by deep UV irradiation followed by development with 1% tetramethylammonium hydroxide aqueous solution. The sensitivity of the heterostructured polymer LB films was improved without loss of the resolution compared with p(DDA- tBVPC53) LB film. The etch resistance of the heterostructured polymer LB films was sufficiently good to allow patterning of a copper film suitable for photomask fabrication.

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