Abstract
Abstract d-Fructose was oxidatively degraded to d-erythrose by atmospheric oxygen with irradiation of a Pyrex-filtered light in the presence of catalytic amount of FeCl3 at near neutral pH range. The reaction proceeded by coupling with the oxidation-reduction cycle of iron ion. d-Glucose-FeCl3 and d-fructose-MnCl2 systems were also found to be susceptible to the catalytic photooxidation.
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