Photooxidation and subsequent biodegradability of recalcitrant tri-alkyl phosphates TCEP and TBP in water

Abstract

Biodegradable organic carbon (BDOC) from OH radical oxidation (UV–H 2O 2) of the recalcitrant industrial anti-foaming agents and flame retardants, tri- n-butyl phosphate (TBP) and tris(2-chloroethyl) phosphate (TCEP), was quantified with respect to the fraction of the TBP or TCEP photooxidized. For 50–96% contaminant oxidation via OH, BDOC was similar in solutions of either compound, and ranged from 0.25 to 0.5 mg L −1 (TBP 0 and TCEP 0 = 5 mg L −1). In addition, for this contaminant oxidation range, complete dehalogenation of TCEP was observed, along with a significant change in pH. Oxidation of TCEP results in both H + and Cl − release, while the TBP mineralization pathway results in CO 2, H 2O, H +, and PO 4 3−. For low μg/L levels of TCEP contamination in treated surface waters, UV–H 2O 2 oxidation of TCEP or TBP would not be expected to impact pH or chloride concentrations, however, a portion of the TCEP or TBP oxidation products, likely in non-halogenated aldehyde form, would become an available carbon source for bacterial growth in storage, distribution, or during further physical treatment.