Abstract
The main spectral-luminescent properties of organometallic complexes of Ti, Zr, and Hf with aromatic ligands are examined. This class of compounds exhibits highly emissive (phosphorescent) ligand-to-metal charge transfer (LMCT) states. The linear dependence of the phosphorescent characteristics of zirconocene on parameters that describe the molecular structure of organic media and also the nature of coordinative (inner- and outersphere) interactions of the phosphorescent metal complex with media molecules is discussed.
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