Photonic liquid crystals of graphene oxide for fast membrane nanofiltration

Abstract

The photonic liquid crystalline (LC) dispersion of graphene oxide (GO) is prepared using centrifugation-induced size-fractionization. Under gravity, a series of successive centrifugations enable large GO sheets to sediment and fractionize into a narrowed size distribution. The resulting large GO sheets display large-area monodomain structures with uniform orientation, forming a photonic LC phase. The single lyotropic LC phase forms at the concentration > 0.34 wt% and structural coloring occurs at the concentration > 0.59 wt%. The structural color with different wavelength is tuned with various concentrations (0.59–0.92 wt%). GO membranes are supported on porous poly(ether sulphone) membranes from photonic LC dispersions by a vacuum-spin method. The photonic GO membrane demonstrates dramatic enhancement of water permeance (169.3 Lm −2 hr −1 bar −1 ), which is 12 times faster than the control GO membrane (13.2 Lm −2 hr −1 bar −1 ). The ion rejection of the photonic GO membrane (45–60%) is also significantly improved, as compared to the control GO membrane (30–48%). Organic dye rejection testing shows that the photonic GO membrane remains as high molecular rejection (> 90%) as the control GO membrane. This work may provide a new way to fabricate ordered GO membranes for fast nanofiltration.