Photonic approach in stacked slabs having periodic holes for enhancing photocatalytic activities.

Abstract

Photonic approaches can improve the efficiencies of photo-electrochemical devices towards CO2 reduction and fossil fuel-free societies. In a system consisting of stacked dielectric slabs having periodic holes with each slab coated by photocatalyst layers at both sides, immersed in water, we show that an incident electromagnetic field is effectively confined in the photocatalyst layers, resulting in the enhancement of the photocatalytic activities. In addition, the antireflection effect was engineered by adjusting the distances between the photonic crystal slabs. Numerical results reveal an enhancement factor of 3 for the absorption of electromagnetic fields at the operation frequency in the 3rd band of the dispersion diagram, compared to the bulk photocatalyst. Our system has the feature of periodic holes allowing the movement of reaction products. An analytical model is developed using the revised plane wave method and perturbation theory, which captures the trends observed in numerical results.