Abstract
This paper addresses the photomobility of O( 1D) atom and the reactions with CF 3I in an argon matrix. The O( 1D) atoms were generated by O 3 as a precursor with 266 nm photons, and its photomobility was testified via the occurrence of the reaction of O( 1D) with CF 3I located at a distance from the O 3 precursor. Matrix isolation infrared spectroscopic observations provide a clear evidence that the translationally “hot” O( 1D) atoms can migrate in an argon matrix at 11 K and react with CF 3I molecules. CF 3OI and carbonyl complex CF 2O ⋯IF are confirmed as primary products, which are formed from the insertion of O( 1D) into C–I and C–F bonds of CF 3I molecules, respectively.
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