Abstract
The quantum yields of formation of chloride ions were determined in photolysis (λ=254 nm) of watercarbon tetrachloride organic phase of ΦCCl4(Cl−)=0.89±0.04 water-chlorobenzene (ΦPhCl(Cl−)=0.137± ±0.005) two-phase systems and saturated aqueous solutions of carbon tetrachloride (ΦCCl4(Cl−)=18.9±5.6 and chlorobenzene ΦPhCl(Cl−)=0.56±0.03. The quantum yields of chloride ions obtained from these systems are compared with partial radiation yields in the same systems. A mechanism for formation of Cl− ions is proposed.
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