Abstract
The linear absorption cross-sections and photodissociation quantum yields for CF3NO have been measured at the wavelengths 694.3 and 632.8 nm (ruby and He(SINGLEBOND)Ne lasers, respectively) in a wide range of total pressure at T = 296 K. The secondary reactions following the photolysis of CF3NO have been studied. The rate constant of the CF3 + CF3NO reaction has been measured. The results obtained show CF3NO photolysis be a convenient source of CF3 radicals for kinetic studies. © 1996 John Wiley & Sons, Inc.
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