Photoluminescence Quenching of CdTe Quantum Dots Generated via Glutathione-Capped Au Nanocrystals.

Abstract

The photoluminescence (PL) quenching of thioglycolic acid (TGA)-capped CdTe quantum dots (QDs) by glutathione (GSH)-capped Au nanocrystals (NCs) were investigated via PL degradated measurement. It was found that the PL of the QDs with several sizes can be effectively quenched by GSH-Au NCs. The size and PL peak wavelengths of QDs have no significant impact on the quenching processing. Through the characterizations of UV-visble absorption spectrum, Zeta potential and steady-state, and time-resolved fluorescence spectroscopy, it was proved that the PL quenching of the QDs by GSH-Au NCs was attributed to static quenching caused by the formation of a QDs-Au complex. The binding parameters calculated from modified Stern-Volmer equation showed that the binding affinities between the GSH-Au NCs and CdTe QDs was in the order of 10(5) L x mol(-1), which indicated that the binding force was larger and the effective quenching occurred. The thermodynamic parameters studies revealed that the binding was characterized by positive enthalpy and positive entropy changes and hydrophobic force played a major role for QDs-Au association. In addition, all the quenching experiments were conducted in the phosphate-buffered saline (PBS) buffer solution at pH 7.4 and the investigation is expected to be applied in the biology.