Photoluminescence properties of Sb3+-activated Ca2YTaO6 dual color emitting phosphors for plant growth LEDs applications

Abstract

Developing highly efficient phosphors-converted white LEDs with excellent emissions characteristics in the blue and deep-red spectral regions, is essential for improving artificial white light for plant growth. Due to the characteristic 3Pn−1S0 transitions (n = 0, 1, 2), Sb3+ is considering as an efficient activator emitting light in the desired deep red and far-red spectral regions. In this paper, we successfully developed Sb3+-doped Ca2YTaO6 double perovskite phosphors, showing broadband doublet emission peaks, in the visible spectral ranges. Computational and experimental investigations were used to confirm the phase purity and structural analysis. The photoluminescence excitation and emission spectra, fluorescence decay curves, thermal stability and CIE chromaticity coordinates have been measured and determined to demonstrate the application potential of the Ca2YTaO6:Sb3+ double perovskites, as suitable phosphors for plant growth acceleration. The blue (420 nm) and deep red (683 nm) emission peaks were observed under 313 nm UV excitation. Efficient energy transfer was observed from the blue emission of the host phosphor to the doped Sb3+ ions, which resulted in an enhancement of the deep-red emission. The appeared dual color emission makes this phosphor a potential candidate for the generation of artificial white light for plant growth.