Abstract

Abstract Photoluminescence (PL) studies are reported on a series of a-SiNx:H alloys prepared by glow discharge, with x up to around 1·1. As x increases, the main PL band broadens and moves to higher energies, and there is a marked reduction in the temperature dependence of the PL efficiency, linewidth and peak energy. The 0·9 eV defect band increases by a small factor and there is only a small reduction in the efficiency of the main band, strongly suggesting that nitrogen introduces few extra dangling-bond defects. Excitation studies show a strikingly large red-shift at low excitation energies up to 0·5eV or more in SiN1·1. This suggests a large increase in tail-state widths, probably due to compositional fluctuations, and this is consistent with most of the other changes in PL behaviour with alloying. We also compare our data briefly with PL from a-Si/SiNx multilayers.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.