Abstract
Sol-gel glass thin films were prepared from tetraethyl orthosilicate in the presence of 4-methoxy-4′-(2-hydroxyethoxy)azobenzene (MHAB), 4-methoxy-4′-(N-(3-triethoxysilylpropyl)carbamoylmethoxy)azobenzene (MTAB) and 4,4′-bis(N-(3-triethoxysilylpropyl)carbamoylmethoxy)azobenzene (DTAB). The optical absorption spectra of the three azobenzenes entrapped in the films were investigated. The trans-cis photoisomerization and the thermal reversion of the azobenzene moiety were studied in the glass films and compared with those in solutions as well as in polymethyl methacrylate (PMMA) thin films. Triethoxysilyl groups linked with the azobenzene moiety had no effect on isomerization reactions. The cis fraction of the three azobenzenes in a photostationary state in PMMA was quite similar to that in solution whereas the photoisomerization was strongly suppressed in sol-gel films due to the rigidity of the matrix. The introduction of one triethoxysilyl group has a slight effect on both photoisomerization and thermal reversion in sol-gel films. Photoisomerization of DTAB with two silylating units was depressed in a sol-sol film because both sides of the azobenzene moiety were fixed to the sol-gel glass matrix.
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