Abstract

Photoionization of the Ce3+ – Ce4+ process has been studied using the random phase approximation with exchange (RPAE) method in the energy region 100-150 eV. The reasonable agreement in magnitude and shape with the recent measurement confirms the suppression effect of the carbon cage in the endohedral fullerene Ce@C+82 photoionization. The reasons for the cause of the confinement resonance and the suppression effect are discussed

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