Photoionization Cross Section of the NH2 Free Radical in the 11.1-15.7 eV Energy Range.

Abstract

The NH2 radical is a key component in many astrophysical environments, both in its neutral and cationic forms, being involved in the formation of complex N-bearing species. To gain insight into the photochemical processes into which it operates and to model accurately the ensuing chemical networks, the knowledge of its photoionization efficiency is required, but no quantitative determination has been carried out so far. Combining a flow-tube H-abstraction radical source, a double imaging photoelectron-photoion spectrometer, and a vacuum-ultraviolet synchrotron excitation, the absolute photoionization cross section of the amino radical has been measured in the present work for the first time at two photon energies: σionNH2(12.7 eV) = 7.8 ± 2.2 Mb and σionNH2(13.2 eV) = 7.8 ± 2.0 Mb. These values have been employed to scale the total ion yield previously recorded by Gibson et al. ( J. Chem. Phys. 1985, 83, 4319-4328). The resulting cross section curve spanning the 11.1-15.7 eV energy range will help in refining the current astrophysical models.