Abstract
This research project involves the design, synthesis and study of the molecules which mimic many of the important aspects of photosynthetic electron and energy transfer. Specifically, the molecules are designed to mimic the following aspects of natural photosynthetic multistep electron transfer: electron donation from a tetrapyrrole excited singlet state, electron transfer between tetrapyrroles, electron transfer from tetrapyrroles to quinones, and electron transfer between quinones with different redox properties. In addition, they model carotenoid antenna function in photosynthesis (singlet-singlet energy transfer from carotenoid polyenes to chlorophyll) and carotenoid photoprotection from singlet oxygen damage (triplet-triplet energy transfer from chlorophyll to carotenoids).
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