Abstract
UV light-induced reactions of o-fluorobenzoyl chloride (FBC) were investigated using infrared spectroscopy in a cryogenic Ar matrix. Photoinduced rotational isomerization from anti- to gauche-FBC was confirmed by comparison with calculated spectra. In addition, photolysis products were found to be ketene species (6-chloro-2-fluoro-2,4-cyclohexadien-1-ylidenemethanone), o-fluorobenzoyl radical, o-chlorofluorobenzene, m-chlorofluorobenzene and CO.
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