Abstract
Broad band irradiation of nitrobenzylidene malonic derivatives in benzene solution in the presence of triethylamine leads to two types of photochemical reactions, photoreduction of the nitro group predominantly, and photosubstitution of the cyano group. The formation of the products is suggested to proceed through a radical ion pair via initial electron transfer, followed by proton transfer, and finally through a sequence of ground state reactions leading to different products.
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Schedule a callMore From: Journal of Photochemistry & Photobiology, A: Chemistry
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