Abstract

A phototunable polymer-stabilised liquid crystal film reflecting both right- and left-circularly polarised light has been successfully fabricated by a washout/refill method. The film was obtained by prefabricating the polymer network with a left-handed helical structure and then refilling a light-driven chiral nematic liquid crystal with a right-handed helical structure into the network. Interestingly, the reflection wavelength and the reflectivity properties can be precisely tuned by UV-light irradiation. A hyper-reflective notch, the reflectivity of which approaches 100%, was achieved in a layer when the pitch lengths of the two opposite helical structures are almost the same. Moreover, their original state can be properly returned by visible-light irradiation.

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