Abstract
Contact ion pair (CIP) formation is especially relevant to the reactivity of organic and organometallic nucleophiles and electrophiles in solution. The authors felt that the intermolecular charge-transfer (CT) absorptions which commonly accompany the interaction of uncharged nucleophiles (donors) with electrophiles (acceptors) could also provide the experimental means to assess CIP behavior. Accordingly they examined the CT excitations from CIPs of carbonylmetallate anions in this study, since they are known to be effective nucleophiles with relatively low ionization potentials.
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