Photoinduced electron transfer from phenanthrimidazole to magnetic nanoparticles.

Abstract

The dynamics of photoinduced electron injection from (E)-1-(4-methoxyphenyl)-2-styryl-1H-phenanthro [9,10-d]imidazole (MPSPI) synthesised using nano TiO(2) as catalyst to Fe(2)O(3) nanocrystal has been studied by FT-IR, absorption, fluorescence and lifetime spectroscopic methods. The binding between nanoparticle and MPSPI is confirmed by binding constant and binding site. The distance between MPSPI and nanoparticle as well as the critical energy transfer distance has been obtained. The free energy change (ΔG(et)) for electron injection has also been deduced.