Abstract
The influence of illumination and annealing on the mechanical and optical properties of amorphous As-S and As-Se films has been studied. The observed compositional dependence of microhardness (Hμ) and photocontraction of the films is in good agreement with the photoinduced (PhI) changes of the optical properties. The photoinduced effects in amorphous arsenic chalcogenide films are explained by the polymerization processes due to the formation of dative bonds between polymeric networks with the concentration of 1021 cm−3.
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