Photofragment Translational Spectroscopy ofn-C3H7I andi-C3H7I near 280 and 304 nm

Abstract

The photodissociation dynamics of propyl iodides n-C3H7I and i-C3H7I near 280 and 304 nm has been investigated with our mini-TOF photofragment translational spectrometer. When a single laser is applied for both the photodissociation of parent molecules and the REMPI of I atom photofragments, the TOF spectra of photofragments I*(2P1/2) and I (2P3/2) are obtained at four different wavelengths for these two iodides. For n-C3H7I, some small vibrational peaks are partially resolved (with separation of approximately 522 cm-1, corresponding to the RCH2 deformation frequency of the fragment n-C3H7) at 281.73, 279.71, and 304.67 nm. These results show that the RCH2 deformation is mostly excited. For i-C3H7I, we obtain some partially resolved vibrational peaks (with separation of approximately 352 cm-1, corresponding to the HC(CH3)2 out-of-plane bending frequency of the fragment i-C3H7) at 281.73 nm only. For n-C3H7I, the partitioning values of the available energy Eint/Eavl are 0.48 at 281.73 nm and 0.49 at 304.02 nm for the I* channel, and 0.52 at both 279.71 and 304.67 nm for the I channel. These energy partitioning values are comparable with the previous results at different wavelengths in the literature. For i-C3H7I, the Eint/Eavl values are 0.61 at 281.73 nm, 0.65 at 304.02 nm for the I* channel, and 0.62 at 279.71 nm, 0.49 at 304.67 nm for the I channel. The potential-energy-surface crossing and the beta values have also been discussed.