Abstract
Cyclopentadienide ligands are exchanged between molecules of di-η 5 cyclopentadienyltitanium monochloride in benzene, and between bis(methyl-η 5-cyclopentadienyl)vanadium dichloride and di-η 5-cyclopentadienylvanadium dichloride in benzene by a photochemical process. A small amount of dimer is produced upon photolysis of benzene solutions containing both 1,1′-trimethylene titanocene dichloride and titanocene dichloride.
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