Abstract

Photoemission studies on barium titanate single crystals are described and it is shown that the photothreshold of a clean surface is 4⋯01 eV. Chemisorption of oxygen obeys the Elovich equation and increases the photothreshold to 4⋯58 eV. The plot of yield versus photon energy consists of three linear portions which are attributed to direct transitions in the bulk. A long wavelength tail obeys a cubic law and is tentatively attributed to defects near the surface. These results are discussed in the light of previous experiments on space charge injection into barium titanate and it is suggested that the traditional model of the metal-semiconductor interface requires modification to explain these results.

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