Abstract

Our valence band photoelectron spectroscopic studies show a temperature dependent spectral weight transfer near the Fermi level in the Fe-based superconductor FeSe1−xTex. Using theoretical band structure calculations we have shown that the weight transfer is due to the temperature induced changes in the Fe(Se,Te)4 tetrahedra. These structural changes lead to shifts in the electron occupancy from the xz/yz and x2 − y2 orbitals to the 3z2 − r2 orbitals indicating a temperature induced crossover from a metallic state to an Orbital Selective Mott (OSM) Phase. Our study presents an observation of a temperature induced crossover to a low temperature OSM phase in the family of Fe chalcogenides.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.