Abstract
Photoelectron spectra of hexafluorobenzene (C 6F 6) cluster anions and its Au complex anion were measured in the gas phase at the photon energy of 3.49 eV, using a magnetic bottle electron spectrometer having ≈ 80 meV resolution. The spectra show unresolved broad features: The vertical detachment energies (VDEs) were determined from the maxima of the spectra. The VDE of (C 6F 6) − n gradually increases by 0.1–0.2 eV with the cluster size ( n=1–8) from 1.56(3) to 2.54(6) eV, and the VDE of (Au-C 6F 6) − anion is 1.99(5) eV.
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