Abstract

We use recapture of near-threshold photoelectrons by postcollision interaction with Auger electrons as an effective method for population of the high-Rydberg states of subvalence ionized Ne ions. The subsequent intermultiplet Auger transitions are detected by high-resolution electron spectrometry. The series of transitions $2{p}^{4}(^{1}D)np\phantom{\rule{0.3em}{0ex}}^{2}D,^{2}F\ensuremath{\rightarrow}2{p}^{4}\phantom{\rule{0.3em}{0ex}}^{3}P$ up to $n=20$ are observed and identified with the help of multiconfiguration Dirac--Fock ab initio calculations.

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