Abstract
Threshold energies (6.1 < E t ⩽ 8.6 eV) are determined for photoelectron emission by 16 inorganic cations in aqueous solution E t values are correlated with gas-phase ionization potentials, solvation and reorganization free energies, standard reduction potentials and ligand field stabilization energies (five transition metals). Dielectric saturation is shown to drastically lower threshold energies.
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