Abstract
The relevant interstate b{sup 3}II, A{sup 1}{Sigma}{sup +}, c{sup 3}{Sigma}{sup +}, and B{sup 1}II spin-orbit induced matrix elements, arising from the Ma (3{sup 2}S) K (4{sup 2}P{sub j}) manifold are treated within the full microscopic Breit-Pauli approximation based on ab initio configuration interaction (CI) wave functions. The determination of these couplings as a function of the internuclear distance of NaK should permit a full treatment of the fine-structure branching ratio K{asterisk}(4{sup 2}P{sub 1/2}(D{sub 1}))/K{asterisk}(4{sup 2}P{sub 3/2}(D{sub 2})) in manifold-meditated photodissociation and in the treatment of interstate perturbations.
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