Abstract
The photodissociation of IBr was investigated by solving the time-dependent Schrödinger equation including the rotational degree of freedom within the wavelength 440–680 nm. Representative samples of 2D slice images and the corresponding total kinetic energy distribution P(E) resulting from photolysis of IBr molecules at ten wavelengths in the range 440–680 nm were obtained. The total kinetic energy distribution P(E) and the P(E) distribution from the respective electronic excited states A, B, C and Y in the range 440–680 nm are also given. Furthermore, the dissociation probability from the respective electronic excited states A, B, C and Y and the branching ratio of Γ(Br*/(Br + Br*)) are determined.
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