Abstract

The photocatalytic degradation of Reactive Black 5, a textile azo dye, has been investigated in aqueous heterogeneous solutions containing semiconductor oxides as photocatalysts. The disappearance of the organic molecule follows approximately a pseudo-first kinetic order according to the Langmuir-Hinshelwood model. CO 2 , NO 3 - , and SO 4 2- ions have been identified as mineralization products. Various commercial photocatalysts were compared with respect to their decolorization efficiency, as well as the production of CO 2 . The effect of pH and H 2 O 2 on the reaction rate was ascertained.

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