Abstract
AbstractA structure occurs in radical‐polymerized polyethylene which leads to formation of a triene on ultraviolet radiation. An inhibition of oxidative processes is observed while the triene or its precursor are being consumed. Subsequent formation of oxygenated products—hydroxyl, carbonyl, and carboxyl—is well behaved and arises from short wavelenght light. A crosslinking reaction is initiated by light of ∼4000 Å wavelength.
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