Abstract
The Fe-treated CNT/TiO₂ photocatalysts mixed with anatase and rutile phase have been developed for the decomposition of non-biodegradable different organic dyes like methylene blue (MB), rhodamine B (Rh.B), and methyl orange (MO) in two conditions as ultraviolet and visible light respectively. The results indicate that all the Fe-CNT/TiO₂ composites proved to be more efficient photocatalysts since degradation of MB at higher reaction rates, tthe decomposition rate of different dyes increases with an increase of Fe³? concentration in composites the highest rate of decomposition of different dyes was noted under UV irradiation. These results can indicate that the large CNT network is facilitate the electron transfer and strongly adsorb dye molecules on the texted photocatalysts, iron is reactive in the photo-Fenton process resulting in high production of OH radicals and also high activity of the photocatalyst. And Fe particles can generate more photoinduced electrons to conduction band of TiO₂ under visible light irradiation. The composites of Fe-CNT/TiO₂ photocatalysts synthesized by a sol-gel method were characterized by BET, TEM, SEM, XRD and EDX.
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