Photocrosslinked norbornene–thiol copolymers: Synthesis, mechanical properties, and cure studies

Abstract

AbstractA number of norbornene‐functionalized resins were prepared and their photoinitiated crosslinking reaction with a multifunctional thiol was studied. Access to these novel resins can be gained by several synthetic routes. The most general of these routes is the [4π + 2π] cycloaddition reaction (the Diels–Alder reaction) of the corresponding multifunctional acrylate ester with cyclopentadiene (CPD) monomer. The photocrosslinking reaction of these resins with multifunctional thiols such as pentaerythritol tetramercaptopropionate (PETMP) is quite rapid and sensitive to low UV dose as well as dose rate. FT‐IR cure studies also indicated that the cure rate slows down dramatically as the conversion approaches the calculated gel points for the systems under study. Mechanical properties of cured thin films of these materials exhibited a wide range of tensile and dynamic mechanical properties, which depended on the structure of starting materials used in the preparation of the norbornene resin and the crosslinking thiol.