Abstract
Photoconduction and magnetic field effect on photoconduction have been investigated as a function of electric field strength, excitation light intensity and wavelength in vacuum evaporated films of m-MTDATA (4,4′,4″-tris(N-(3-methylphenyl)-N-phenylylamino) triphenylamine), the starburst amine commonly used as hole-transporting material in organic light-emitting diodes. The photocurrent is found to be generated by the singlet exciton dissociation at the illuminated Al anode/m-MTDATA interface in accordance with the 1-D Onsager mechanism and in the bulk of the sample in terms of the 3-D Onsager model of e–h pair separation. The surface component of photocurrent is magnetic field independent whereas the bulk-generated photocurrent is influenced by external magnetic field of the hyperfine coupling (HFC) as well as fine structure modulation (FSM) scales.
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