Abstract
The synthesis and characterization of two novel photochromic diarylethenes containing boron difluoride chromophores is described. The boron difluoride chromophores are connected directly to the thiophene rings and participate in the photoisomerization reaction. X-ray single crystal structure analysis of the diarylethenes indicates that intermolecular planar π–π interactions are significantly alleviated, due to various intermolecular non-covalent bondings. Therefore, they show almost the same fluorescent properties in the solid state as in dilute chloroform solutions. These two diarylethenes show typical photochromic properties in chloroform and also in poly(methyl methacrylate) film. During the photochromism, fluorescence of the diarylethenes could be reversibly tuned.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
