Abstract
Validation of the mechanism of tetrachloroethene photochlorination at low C2Cl4 concentrations was investigated. The reaction was examined in carbon tetrachloride solution. For initial tetrachloroethene concentrations below 2 mol I−1, the solvent participates in a free-radical chain photochlorination. The presence of CCl4 disturbs the course of this particular chain reaction and influences the duration of the induction period.
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