Abstract
The principal products (up to 70% of theoretical yield) of the UV irradiation of Schiff's bases derived from β-naphthylamine in several primary alcohols are benzo[f]quinolines, i.e. the reaction involes the incorporation of moieties derived from the solvents. The effect of the nature of the substrate and solvent and of experimental conditions on the yields of these and other products was investigated. NMR data for 9 substituted benzo[f]quinolines are tabulated and the stereochemistry of some dimers derived from Schiff's bases was investigated by NMR spectroscopy.
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