Abstract
Irradiation UV (254 ou 213 nm) de complexes W(CO) 5 (alcene) avec alcene=C 2 H 4 , C 3 H 6 et pentene-1 dans le methylcyclohexane. La perte relative de l'alcene est deux fois plus importante a 313 nm qu'a 254 nm. En outre la perte en compose ethylenique est triplee selon l'ordre C 2 H 4 <C 3 H 0 <C 5 H 10 . Mecanisme. Spectres IR, UV, visible
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